Match List I with List II. List I (Complex) List II (Type of isomerism) A. [Co(NH3)5(NO2)]Cl2 I. Sol

Q: What is NEET?

NEET is a competitive examination conducted in India. This question is from the 2024 NEET Chemistry paper.

Q: How can I prepare for NEET Chemistry?

To prepare for NEET Chemistry, practice previous year questions (PYQs), understand concepts thoroughly, and solve mock tests regularly. This 2024 question covers Coordination Compounds topic.

Q: What is the difficulty level of this question?

This NEET 2024 Chemistry question has a medium difficulty level and is marked as an important question and is one of the most repeated questions.

Q: Where can I find more NEET previous year questions?

You can find more NEET previous year questions on AspirantMitraa. Browse by subject, topic, year, and difficulty level to practice effectively.

Question

Match List I with List II. List I (Complex) List II (Type of isomerism) A. [Co(NH3)5(NO2)]Cl2 I. Solvate isomerism B. [Co(NH3)5(SO4)]Br II. Linkage isomerism C. [Co(NH3)6][Cr(CN)6] III. Ionization isomerism D. [Co(H2O)6]Cl3 IV. Coordination isomerism. Choose the correct answer: (1) A-II, B-III, C-IV, D-I (2) A-I, B-III, C-IV, D-II (3) A-I, B-IV, C-III, D-II (4) A-II, B-IV, C-III, D-I

Accepted Answer

Correct Answer: a — A-II, B-III, C-IV, D-IStep-by-step Solution:The types of isomerism in coordination compounds are identified as follows:[Co(NH₃)₅(NO₂)]Cl₂: The NO₂ ligand can bind through nitrogen (nitro) or oxygen (nitrito), giving linkage isomerism. Hence A matches with II.[Co(NH₃)₅(SO₄)]Br: The SO₄²⁻ ion can be inside or outside the coordination sphere, leading to ionization isomerism. For example, [Co(NH₃)₅SO₄]Br and [Co(NH₃)₅Br]SO₄. So B matches with III.[Co(NH₃)₆][Cr(CN)₆]: This is a coordination compound where both cation and anion are complexes. Ligands can exchange between the two complex ions, giving coordination isomerism. Hence C matches with IV.[Co(H₂O)₆]Cl₃: Water molecules can be inside or outside the coordination sphere, leading to solvate isomerism (hydrate isomerism). For example, [Co(H₂O)₆]Cl₃ and [Co(H₂O)₅Cl]Cl₂·H₂O. So D matches with I.Thus, A-II, B-III, C-IV, D-I corresponds to option a.Key Concepts: Isomerism in coordination compounds: linkage isomerism, ionization isomerism, coordination isomerism, solvate (hydrate) isomerism.

Master NEET with Our Test Series

More Questions from Coordination Compounds

Frequently Asked Questions

Master NEET with Our Test Series

More Questions from Coordination Compounds

Frequently Asked Questions